Phys 402/OEPE 542: Quantum Mechanics II

Sprinf 2018

Topics Covered in Lectures

 

 

Lecture Number

Date

Content

Corresponding Reading material

1

Feb. 06

Review of the content of the syllabus; review of basic topics covered in Phys. 401

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2

Feb.13

Physical equivalence of Hamiltonians that differ by a possibly time-dependent multiple of the identity operator, solution of the time-independent Schrodinger equation for a delta-function potential; The uncertainty principle, the minimum uncertainty states, and the simple harmonic oscillator (SHO) as the system having minimum uncertainty states as an energy eigenstate, the unique role played by SHO in classical mechanics (behavior of a system near a stable equilibrium.)

Pages 237-241& 185-186 of Shankar

3

Feb. 15

Solution of the time-independent Schrodinger equation for a SHO in the position representation: Hermit polynomial, energy spectrum, and energy eigenfunctions

Pages 189-196 of Shankar

4

Feb. 20

Algebraic solution of the time-independent Schrodinger equation for a SHO: Ladder operators, construction of the eigenvector and eigenvalues of the Hamiltonian

Pages 202-206 of Shankar

5

Feb. 22

Properties of the raising and lowering operators, representation of the linear operators in the energy basis of a SHO, calculation of the product of position and momentum uncertainties in the energy states of a SHO

Pages 206-209 of Shankar

6

Feb. 27

Propagator for SHO; Pilot-wave interpretation of QM: Quantum potential and quantum analog of Hamilton-Jacobi equation in 1 dimension; probability current density, continuity equation for probability, and its local conservation, the Pilot-wave interpretation, application to stationary states and the semiclassical approximation

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7

Mar. 01

The WKB wave function, application of the WKB approximation for the determination of the spectrum of a potential with a discrete spectrum (general description of the idea, no examples); Quantum mechanics of a particle with configuration space R^N: The Heisenberg algebra h_N and the uniqueness of its unitary representations, the Hilbert space L^2(R^N) and the operators representing the position and momentum observables

Pages 435-438 & 141-142 of Shankar

8

Mar. 06

Consequences of inclusion of adding a function of position to the standard momentum operators and unitary equivalence of the unitary representations of the Heisenberg algebra h_N, the position representations of the time-dependent and time-independent Schrödinger equations for standard Hamiltonian operators in N dimensions; eigenvalues and eigenfunctions of the Hamiltonian for a particle in an infinite potential well; appearance of degeneracies.

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9

Mar. 08

Symmetry in QM: Review of the concepts of canonical transformations and symmetry transformations in CM; infinitesimal symmetry transformations and their generators; Nöther’s theorem in Hamiltonian formulation of CM; Unitary transformations of the Hilbert space as the quantum mechanical analog of canonical transformations; symmetry transformations and their generators in QM; a quantum analog of Nöther’s theorem

Pages 279-289 of Shankar

10

Mar. 13

Translations and translational symmetry, reflections and parity operator(s), antilinear symmetries, time-reversal transformation and time-reversal symmetry

Pages 289-303 of Shankar & 20-24 of Supplementary Material #1

11

Mar. 15

Adjoint of an antilinear operator, properties of the time-reversal operator; Rotations in 2D as a classical canonical transformation, the definition of the rotation operator, its linearity and unitarity, angular momentum operator L_z as the generator of rotations, derivation of the expression for the rotation operator in terms of L_z

Pages 20-24 of Supplementary Material #1 and 305-310 of Shankar

Midterm Exam 2

Mar. 20

 

 

12

Mar. 21

Commutation relations for position, momentum, and angular momentum operators in 2D, Campbell-Backer-Hausdorff identity, its proof, and application in computing the effect of a finite rotation on the position and momentum operators in  2D, rotational symmetry in 2D: Central potentials, solution of the eigenvalue problem for L_z in 2D and the quantization of angular momentum.

Pages 310-315 of Shankar

13

Mar. 22

Comment on canonical and  unitary transformations and their difference with active and passive transformation of classical and quantum systems; time-independent Schrödinger equation for a central potential in 2D, solution for the isotropic infinite-well potential in 2D

Pages 315-318 of Shankar

14

Mar. 27

Angular momentum in 3D: Commutation relations among X_i, P_i, and L_i, Lie algebras, so(3) and su(2); the rotationally invariant quantum systems, the square of total angular momentum and its commutation with L_i’s

Pages 318-321 of Shankar

15

Mar. 29

Construction of an orthonormal set of eigenvectors of L^2 and L_3 using the so(3) algebra relations

Pages 321-324 of Shankar

16

Apr. 03

Interpreting the analysis of the preceding lecture as the construction of the unitary irreducible representation of so(3); the half-integer representations and the intrinsic angular momentum (spin), expressing the total angular momentum J=(J_1,J_2,J_3) as the sum of orbital angular momentum and spin, derivation of the matrix representation of Ji in the unitary irreducible representations of so(3)

Pages 324-329 of Shankar

17

Apr. 05

Position representation of the common eigenvectors of L_3 and L^2 in spherical coordinate: Spherical harmonics and associated Legendre polynomials

Pages 333-338 of Shankar

Spring Break

 

 

 

18

Apr. 17

Solution of the time-independent Schrödinger equation for a standard rotationally invariant Hamiltonian operator in 3D (part 1): Derivation of the differential equation for the r-dependent part of the energy eigenfunctions, equivalence to a particle moving in a half-line, implications of the self-adjointness and boundary condition at r=0 and r=infinity.

Pages 338-342 of Shankar

19

Apr. 19

Solution of the time-independent Schrödinger equation for a standard rotationally invariant Hamiltonian operator in 3D (part 2): Boundary condition at r=0; The hydrogen atom: Differential equation determining the energy eigenfunctions and its reduction to a 2nd order linear homogeneous equation with a regular singularity at r=0.

Pages 342-343 &353-354 of Shankar

20

Apr. 24

Application of Frobenius method to determine the energy eigenfunctions of the hydrogen atom and its energy levels, the position wave functions for the ground and first excited states of the hydrogen atom, the degeneracy of the energy eigenvalues

Pages 354-359 of Shankar

21

Apr. 26

The emission and absorption energy and transition between energy levels of the hydrogen atom and the wavelength of the emitted and absorbed electromagnetic waves; Spin as internal angular momentum, the Hilbert space for a particle with spin, the total angular momentum and effect of a rotation on the states of a spinning particle, basis in which L^2, L_z, S^2, and S_z are diagonal, the spin-half particles, spinors, Pauli matrices; the matrix form of a finite rotation for spin-1/2 particles

Pages 361-368 & 373-385 of Shankar

22

May 03

Dynamics of a spin ½ particle in a constant magnetic field, effects of placing a hydrogen atom in a constant magnetic field

Pages 385-392 & 397-399 of Shankar

Midterm Exam 2

 

 

 

23

May 08

QM of a Many-Particle system - Mathematical Preliminaries: Tensors, covariant and contravariant tensors, the vector space of tensors, their bases, and tensor product; The tensor algebra

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24

May 10

Inner product on the tensor product of N inner-product spaces, the tensor product of linear operators, their linearity, composition, and Hermiticity, Classical mechanics of a system of two distinct particles moving in a straight line: States, observables, Hamilton’s equations, transformation to center of mass and relative coordinates and the corresponding conjugate momenta; Quantum mechanics of a system of two distinct particles moving in a straight line: The Hilbert space, state vectors, and observables

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25

May 15

The position and momentum operators for a quantum system of two distinct particles moving in a straight line, the canonical commutation relations, the position and momentum kets and bras, the position wave function, the standard Hamiltonian when the particles do not interact and its energy eigenvalues, the standard Hamiltonian when there is only an inter-particle interaction depending on the relative coordinates, the energy spectrum and energy eigenfunctions for a pair of particles with a linear force between them (attached to one another by a spring); Quantum mechanics of an identical pair of particles: Bosons and fermions; the symmetric and antisymmetric tensor product, their orthonormal bases and completeness relation

Pages 247-258 & 260-266 of Shankar

26

May 17

Measurement of observables for an identical pair of particles, the position measurement, position wave function, and probability of localization of pairs of identical bosons and fermions in space, The Pauli Exclusion Principle, formulation of QM for N distinct and identical particles, the permutation group and totally symmetric and antisymmetric tensor product, the Hilbert space for N identical bosons and fermions

Pages 267-273 of Shankar

Note: The pages from the textbook listed above may not include some of the material covered in the lectures.